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Also known as: Pyridinium Chlorochromate Oxidation, Corey-Suggs Oxidation
A mild, selective Cr(VI) oxidant that converts primary alcohols to aldehydes (without over-oxidation to carboxylic acid) and secondary alcohols to ketones. The anhydrous conditions (CH₂Cl₂) prevent the aldehyde hydrate from forming.
The alcohol displaces chloride from PCC to form a chromate ester.
E2-like elimination gives the aldehyde (or ketone) and Cr(IV) species. Under anhydrous conditions, the aldehyde is stable and doesn't get further oxidized.
Anhydrous CH₂Cl₂ prevents over-oxidation
1-Hexanol
PCC, CH₂Cl₂
Hexanal
Benzyl alcohol
PCC, CH₂Cl₂
Benzaldehyde
The go-to reagent when you need an aldehyde from a primary alcohol. Simple and reliable.